Less chemically, its due to several factors. Aluminum is softer, more flexible thus less likely to cause damage to the bark of deciduous material where a flawless complexion is a desirable attribute. Copper is harder so a particular gage of wire has more bending strength than that of aluminum which is sometimes necessary for conifers. There are exceptions regarding them both, some Deciduous have very hard wood and reaching for copper could be appropriate. And in the same vein, plenty of conifers may not be hardened off enough yet to justify the additional expenditure of copper wire, so aluminum would be much more sensible to use. One point of consideration is that many consider copper wire more attractive, so if one is planning on showing a tree with wire present, you may opt to use copper for those purposes alone.