I would only use fiber glass as the mesh to help support a larger slab. Any mesh that is inert when in contact with concrete is okay. Plastic mesh, dry wall taper's mesh, expanded steel mesh, fiber glass mesh, all are good each better for for a different size project. Metal mesh, if not stainless steel should be coated to be corrosion resistant. Though for pots, this is probably over kill. In a bridge deck built for 75 year minimum life span, coated is necessary. So the support mesh is the only place I would use fiber glass if I used fiber glass at all, it is completely optional.
The fibers that are added to the concrete mix are usually little pieces of plastic, shaped like bow ties, or little I beams, a straight piece with a short cross bar at each end. They can be polyethylene, or cross linked polyethylene, or polypropylene or any other plastic. They could be other materials, but the plastic fibers are the cheapest. They usually come in a one pounds, 5 pound, or larger bag. They are light, the smallest bag of fibers will be almost the same volume as a 50 pound bag of cement. One bag will be good for hundreds of pots.
Does this clear it up?