I think I'm following along with most of what you're saying, but I was only mediocre at chemistry in high school. pH is really a proxy of CO3^2-, HCO3^-, and OH^-, but the one that is detrimental to plants is HCO3^-? Without a reverse osmosis system, I'm not entirely sure what I could do to deal with total alkalinity, thus the citric acid additions. Is pH a decent enough proxy that using citric acid will provide some kind of improvement? To double check that the pH adjustment will help solve my issues, I've been watering the stressed plants with a watering can plus a small amount of vinegar, and double checking with my pH meter before watering. I've started to see a slight improvement in the two weeks since I started, which I found encouraging
I'm not particularly out there in my substrate choices. Most of the trees are in 1 part potting soil, 1 part perlite for development. Most of the others are akadama and pumice, or Aoki blend. The shitakusa are a mix of Aoki blend and potting soil
Are you using a siphon/Venturi fertilizer injector? The fertilizer injector is definitely a luxury that is technical overkill, but I had already been wondering about getting one for fertilizing anyway